Course Details
Subject {L-T-P / C} : CY2101 : Hydrocarbons and Their Functional Groups { 3-0-0 / 3}
Subject Nature : Theory
Coordinator : Prof. Niranjan Panda
Syllabus
Alkenes and alkynes: Synthesis through elimination, electrophilic addition reactions, addition of halogens, hydrogen halides, water, regioselectivity, oxymercuration-demercuration, addition of borane, hydrogenation, oxidation, ozonolysis, regio- and stereochemistry of addition reaction conjugated dines, addition to conjugated dines alkyne synthesis, addition of halogen, hydrogen halide, water, boranes, hydrogenation, acetylide ion Aromaticity, antiaromaticity, electrophilic and nucleophilic substitution reactions in aromatic systems: nitration, halogenation, sulfonation, Friedel-Crafts reactions, reactions of substituted benzene: electronic effect of substitutents, important reactions of phenols, thiols, aromatic amino compounds and naphthalene. Nucleophilic attack on aromatic species: substitution of hydrogen, substitution of atoms other than hydrogen, substitution via aryne intermediates. Synthesis and reaction of heteroaromatic compounds- furan, pyrrole, thiophen and pyridine, indole, quinoline, isoquinoline.
Course Objectives
- To know how to synthesize unsaturated organic compounds?
- To understand the reactivity of unsaturated compounds
Course Outcomes
1) Provides the basic foundation to understand the higher level of organic chemistry <br />2) Gives an idea about common organic compounds and their reactivity
Essential Reading
- 1. P.Y. Bruice, Organic Chemistry, Pearson Education , 3rd Edition, 2009
- 2. J. Clayden, N. Greeves, and S. warren, Organic Chemistry, Oxford University Press , Second edition, 2012
Supplementary Reading
- Carey & Sundberg, 2. Advanced Organic Chemsitry Part-B, Springer , 5th edition, 2007
- Singh, J., Advanced Organic Chemsitry, Pragati edition , 2nd edition, 2016